Yeah like that, but as you see stone skin (and all the other enchants) won't give their bonus at all if the unique has 2+ immunities already, so its just 2x the base defense.
Cold immunity is nice to have because of the slow %, and poison immunity prevents it disabling regen, but fire/light/magic really don't matter when a demon has 500k+ hp. And all get fire immune if you have flickering flame on merc.
I still haven't found any ranged demons that carry their physical attack added to range damage, they all have just base missile damage with no bonuses at all so might as well be 0 damage on all ranged options.
Its a bit interesting you CAN bind defilers even though you can't revive them as a necro. They won't use impregnate though, so no pain worms. Though they do use the silly melee attack. You can bind pain worms at least. Can't bind festering appendages from baal.
At least normally, some people are reporting a glitch that lets you bind non-demons which presumably might let you bind
anything, and I'd love to get some unique festering appendages going