Here's a recent paper on valproic acid I just came across finger:
http://www.sciencedirect.com/science/article/pii/S0006899314010245"Highlights
• The role of HDAC inhibition in alcohol reward was investigated
• Valproic acid (VPA) reduced voluntary ethanol consumption and preference
• VPA has no effect on tastants, saccharin and quinine, intake and preference
• VPA blocked Ethanol-induced conditioned place preference
• VPA reduced HDAC activity in the NAcc but had no effect on blood ethanol metabolism"
As for your question.. no lol. You'd be better off with something else that could reduce pain. Alcohol isn't really robust in its anesthetic effect, it'd take, as cloud/nmu said, enough that would impair you.
Here's a paper looking at caffeine, nicotine, thc, and alcohol:
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3878772/Peep the section under alcohol & performance