No one has posted, but I've got something to add.
I have now seen a 2sk/5ll/89rlvl caster amulet (with 4 random affixes). It is possible. (67>45: 67+10+3*4=89)
To summarise this mess:
I now explicitly remember the 75% Arreat Summit statement being wrong, it always has been, I just could not recall when I made my initial post or even after. Instead of questioning Arreat Summit, I questioned the rlvl formula, modifying N so it would equate to 95. Additionally I subtracted affixes on a whim. Considering I haven't crafted in a decade I probably should not have done that.
Lesson learnt. Don't use Arreat Summit, use MagicSuffix.txt and MagicPrefix.txt. Hopefully they are still 100% valid.
Arreat Summit easter egg, fitting for this situation:
https://classic.battle.net/images/My monologue ends here.