jack up the front of the car about 6 inches
that will set the hoses to an incline/decline however you look at it. the air should come to the top of the radiator/over flow easier.
these should have a over flow tank that you top up and it pulls fluid into the radiator.
the only place for an air pocket would be the heater core at that point, and because the car is tilted up, air should be easier to get out.
if you pull the old thermostat out, might as well replace it.
dont forget to use either a 50/50 or 70coolent/30water
distilled works best, as there are less minerals.
if it still over heats do a good look around for leaks/seepage
when you start it, let it warm up dont shut the hood until the fans kick on. when the fans kick on thats when the thermostat should release and let the hotter coolent swap out with the cooler coolent play with the heater/ac while its warming up