Answer
The answer is (A). Since it must happen, the probability is actually 1 (100%).
Explanation: Firstly, consider 2 men, one starting from the top of the mountain and hiking down while the other starts at the bottom and hikes up. At some time in the day, they will cross over. In other words they will be at the same place at the same time of day.
Now consider our man who has walked up on one day and begins the descent the next day. Imagine there is someone (a second person) shadowing his exact movements from the day before. When he meets his shadower (it must happen) it will be the exact place that he was the day before, and of course they are both at this spot at the same time.
Contrary to our common sense, which seems to say that this is an extremely unlikely event, it is a certainty.
NOTE: There is one unlikely event here, and that is that he will notice the time when he is at the correct location on both days, but that was not what the question asked.