your dps stat is your approximate auto attack dps. granted this does not take into account ele damage or skill damage. But if you know these stats you can get an approximate. Your damage is calculated multiplicatively by each modifier, so if we simply start with your dps which has already been calculated via (wpn dmg x IAS x (CC x CHD) = Sheet DPS or sDPS)
Lets say you have 1mil sheet dps(for simplicity). this means if you don't put a skill on your left click your basic auto attacks will result in about 1 millioin damage per second.
Now lets put a skill there. How about a 200% weapon damage ability. This skill's dps will be 200% of your sheet dps when used, so ~2mil. (sDPS x Skill Weapon%)
Lets make a decent assumption that you have some elemental gear, how about 50% fire and this ability is a 200% weapon damage fire skill. This ability does ~3mil dps. (sDPS x Skill Weapon% x +Ele%)
Now lets make another assumption that you have some +Skill% damage, 30% seems reasonable. This skill now does ~3.9mil dps (sDPS x Skill Weapon% x +Ele Dmg% x +Skill Dmg%)
The numbers: sDPS = 1,000,000 Skill Weapon% = 200% of total or 2 + Elemental Damage% = +50% or 150% of total or 1.5 +Skill Damage% = 30% or 130% of total or 1.3
Skill DPS = 1,000,000 x 2 x 1.5 x 1.3 = 3,900,000 or 3.9mil DPS
So, while your sDPS shows you 1million, using some simple math you can come to a reasonable conclusion that the skill you are using with element and skill damage factored in, you are doing 3.9 million DPS while using that skill.
So in a way, yes, the dps calculation accurate if you know how to use it properly.